Sensitization of austenitic stainless steels by welding. Stainless steels are ironbase alloys containing 10. Practical guidelines for the fabrication of high performance austenitic stainless steels first edition 2010. Pdf analysis of sensitization of austenitic stainless steel. Sensitization behaviour of 1112% cr aisi 409 stainless steel. Austenitic stainless steels containing more than about 0. Ferritic stainless steels are nonhardenable fecr alloys. Reduced carbon ati 316l alloy is resistant to sensitization. Stainless steel transported in coiled from is under tension and represents a. Interest in the sensitization behavior of type 304 has been rekindled by the recurrent problem of pipe cracking in boiling water reactors, and the subject is of major. Timetemperature sensitization diagrams were developed for two heats of sheet materials of types 347, 304l, and 316l stainless steels.
It is understood that sensitization is a phenomena which occurs mainly in austenitic stainless steel during fabrication which include welding. Sae air844 sensitization and corrosion in stainless steel filters standard by sae international, 11011995. Simple green australia this sds has been revised in the following sections. The primary alloying additions are chromium and nickel. Mode 3 sensitization corresponds to the sensitization found in titanium stabilized stainless steels with a high kaltenhauser ferrite factor kff or fully ferritic stainless steel such as aisi 40911,12. Interpretive report on the sensitization of type 304. Inter granular corrosion can be detected by ultrasonic and eddy current methods. While it stabilizes the ferritic stainless steels have a cr content of 1128% with a carbon content below 0. Evidence is found that the depletion of molybdenum plays an important role in the sensitization of type 316 stainless steel. Ferritic stainless steels such as the 430 series, 29cr alloys, and xm alloys all can be tested by the astm a763 methods to find sensitization. How to avoid sensitization when welding austenitic stainless steels. Stainless steel alloys are not considered hazardous in solid rodbar, wire, tubing, strip and sheet form.
Personnel handling this material must make independent determinations of the suitability and completeness of information from all sources to. Continuous cooling sensitization and its evaluation in austenitic stainless steel en 1. Sensitization of austenitic stainless steels total materia. Corrosion resistance,austenitic stainless steel, sensitization, hardness, crcarbides i. Reference is often made to stainless steel in the singular sense as if it were one material. The sensitization was assessed by scanning electron microscopy sem according to astm a262 and by the double loop electrochemical potentiokinetic reactivation test dlepr. Sensitization behavior of gnaw austenitic stainless steel joints.
Chromium carbides form in the grain boundaries of some austenitic stainless steels in the temperature range 500 850c. Taken from astm specifications for plate, sheet and strip when available or from company data sheets. Stainless steels are iron based alloys that contain a minimum of 10. Pdf sensitization and tunneling corrosion of austenitic. Austenitic stainless steel aisi 316 as experimental material had been chosen. Zapp stainless steel 301, 302, 304, 304l, 305, 309, 310, 310s, 316, 316l, 321, 347, 350, 430, 177ph, 18sr version date.
In addition, the stainless steel immediately under the layer often is sensitized due to carbon contributed by the process, and the entire bulk metal may be sensitized by the temperature and time required for the process. Evaluation of sensitization in stainless steel 304 and 304l. Oct 29, 2017 sensitization happens when a stainless steel is held at a temperature of 425 815c and chromium carbides precipitate at the grain boundaries. Austenitic stainless steels may become sensitised if they are heat treated or used at temperatures in the range 500 850c. The objective of this research is to determine the sensitivity of nonlinear ultrasound to the presence of sensitization in austenitic stainless steels. Understanding the effect of uniaxial tensile strain on the. Astm a 736 sensitization testing of ferritic stainless steel.
Mitraa adepartment of metallurgical and material engineering, jadavpur university, kolkata 700032. Although its more commonly thought of with austenitic stainless steels, sensitization can also affect the ferritic stainless steels. Sensitisation study of normalized 316l stainless steel. Sensitization and tunneling corrosion of austenitic type 347 stainless steel. This precipitation happens because the carbides are insoluble at these temperatures. The intergranular corrosion resistance was characterized using astm a262 test methods and the double loop electrochemical potentiodynamic reactivation testing epr. The mechanism of sensitization of austenitic stainless steel. Similarly, the sensitization to intergranular corrosion of aisi 316 type stainless steel was evaluated quantitatively both by microscopy and by electrochemical tests. Type 304 stainless steel is used for piping carrying hightemperature, pressurized water ca. Influence of post welding heat treatments on sensitization. Types 405, 409, 430, 422 and 446 are representative of this group. Sensitization behaviour of 1112% cr aisi 409 stainless. Analysis of corroded stainless steel bolts summary. Material safety data sheet stainless steel 301, 302.
Contributing factors can include heating and cooling through specific temperature ranges. Pdf an overview of sensitization dynamics in ferritic. Table 1 application of evaluation tests for detecting susceptibility to intergranular attack in austenitic stainless steels note 1for each corrosion test, the types of susceptibility to intergranular attack detected are given along with the grades of stainless steels in which they may be found. The phenomenon is known as sensitization, which is alloy is sensitive to corrosive attack, or weld decay, for the way the sensitized region in the hazheat affected zone is eaten away by corrosion. Sensitization refers to the susceptibility of materials to intergranular corrosion and comes about by a combination of factors in the materials composition and treatment. The results show that stabilization by itself is not sufficient to render austentic stainless steel immune to sensitization. The chromium concentration along grain boundaries of sensitized austenitic 308 stainless steel was measured as a function of sensitizing treatment. A study on the failure of aisi 304 stainless steel tubes in a. Identification of the substancemixture and of the companyundertaking. By optimizing the cn balance of the present sus420j1, we could develop and bring to market a new stainless steel, nssc 420j1m, which has the same hardenability.
Besides the problem of low ductility and poor toughness of ferritic stainless steel, welds due to the microstructures characteristics. Sensitization is a phenomenon that can occur in austenitic. The samples for the study of sensitization were solution annealed on 1100 c for 60 min followed by water quenching and then sensitization by isothermal annealing on 700 c. Material safety data sheet stainless steel 301, 302, 304. Austenitic stainless steels have many advantages from a metallurgical point of view. In addition to the thermodynamic effect of high chromium concentrations which inhibit sensitization by raising the chromium concentration in the matrix at the carbidematrix interface, the requirement of a reduced intercarbide spacing along sensitization of austenitic stainless steel 151 the grain boundaries is an additional cause of the. This chromium reacts with the air and forms a very thin but very tenacious chromium oxide layer which is what prevents stainless from rusting. The epr test has found wide use as a means to provide a numerical level of sensitization in studies of the effects of sensitization on intergranular corrosion and intergranular stress corrosion cracking behavior.
The aim of this study is to conduct a detailed analysis of the various weld sections within a. Although these carbide formations occur in every kind of stainless steel, it is a little bit slower in austenitic stainless steel. It is also important to know that within the sensitization range there is a critical midrange from about 1100. And there is a word called sensitization which is a very important phenomenon in stainless steel. Sensitization of austenitic stainless steels total. In order for the carbide to precipitate, it must obtain chromium from the surrounding metal.
In type 316l with high levels of nitrogen, several different phases are found at the grain boundaries, which affects the. Austenitic stainless steels have a wide range of application in the energy industry, but the corrosion resistance of the stainless steel can be reduced by. The conformity of epr test methods single and double loop and strauss test on 18cr12ni2. How to avoid sensitization when welding austenitic stainless. Time temperature sensitization tts diagrams for types 347. However, if subsequent processing involves grinding, melting, welding, cutting, or any process that causes release of dust or fume, hazardous levels of dust. Curves were derived from corrosion data obtained by the boiling nitric acid test of specimens heated to temperatures between 700 and 1500 f for times up to 35,000 hr. Na ld50 of material not established lc50 of material not established.
First aid measures first aid skin seek medical help for serious cuts or lacerations or if irritation from contact with dusts persists. This is a wellknown phenomenon called sensitization that. Methods to avoid material sensitization during welding for. Stainless steel health product declaration page 1 of 11 created via. An overview of sensitization dynamics in ferritic stainless steel welds. Numerous papers have been published on the microstructures of duplex stainless steel weld metal and hazs, but detailed studies of the as welded structures and their susceptibility to sensitization are limited. Smil used mainly ferritic steels for its applications till now. Certain alloys, when exposed to a temperature characterized as a sensitizing temperature, become particularly susceptible to. Influence of heat treatments on the microstructure and. Pdf analysis of sensitization of austenitic stainless steel by. Certain alloys, when exposed to a temperature characterized as a sensitizing temperature, become particularly susceptible to intergranular corrosion.
The different soaking times at these temperatures were 30 mins, 1 hour, 2. This work presents a systematic investigation of the influence of time and temperature in the sensitization of stainless steel aisi 304l, aisi 316l, aisi 321 and aisi 347 pipes used in petroleum refining plants. Austenitic stainless steel 304l has a lower carbon content than 304, so sensitization should be less severe and slower than 304. Sensitization refers to the precipitation of carbides at grain boundaries in a stainless steel or alloy, causing the alloy to be susceptible to intergranular corrosion. Determination of susceptibility to intergranular corrosion. Conditions that can promote damaging corrosion in stainless steel filter screens are discussed and recommendations are listed for minimizing corrosion damage. Guidelines on development of new stainless steel with better corrosion resistance it has been reported that in order to restrain the sensitization of stainless steel, it is effective not only to reduce the content of carbon but also to add nitrogen. This means that the increase in heating temperature led to the increase of pitting intensity. Austenitic stainless steels have a tendency to form chromium depleted zones at the grain boundaries during welding and heat treatment, where. The heat affected zones haz of welds may also be sensitised in some circumstances. Content in descending order of quantity this section lists materials in a product and the substances in each material based on the inventory threshold for each material.
Corrosion resistance,austenitic stainless steel, sensitization, hardness. Stainless steel transported in coiled from is under tension and represents a significant source of. Stainless steel, alloy, pitting corrosion, polarization, xray diffraction. Standard test method for electrochemical reactivation epr. Stabilization and sensitization of stainless steels onepetro. Sensitization is a phenomenon that can occur in austenitic stainless steel. Developments in stainless steel instrumentation tube fittings. C is more negative than that of nonheated specimen by a value of 284 mv. Here, as a feasibility study for application of nondestructive evaluation for sensitization using magnetic measurement, heat treated ni base alloy and austenitic stainless steel were scanned by a magnetic field sensor. Cross section of conventional gas nitrided stainless steel. Mti received five stainless steel bolts from a marine environment.
Sensitization evaluation of the austenitic stainless steel aisi 304l, 316l, 321 and 347. The present work was concerned with the study of the sensitization and desensitisation of 316l steel at the normalizing temperatures of 750 9500 c and soaking times of 0. Sensitization evaluation of the austenitic stainless steel. Detection of sensitization for 600 alloy and austenitic.
Sensitization happens when a stainless steel is held at a temperature of 425 815c and chromium carbides precipitate at the grain boundaries. Stabilized austenitic stainless steel such as type aisi 347 ss and aisi 321 ss are widely used in components designed for high temperature applications like nuclear reactors, boilers, superheaters and chemical reactors because of their good resistance to sensitization and creep deformation. The second problem with welding austenitic stainless steel is hot cracking. Sensitization refers to the precipitation of carbides at grain boundaries in a stainless steel or alloy, causing the steel or alloy to be. Stainless steels austenitic stainless steels include the 200 and 300 series of which type 304 is the most common. Sensitization and tunneling corrosion of austenitic type 347 stainless steel article pdf available in corrosion houston tx 542. How to avoid sensitization when welding austenitic. Quantitative xray microanalysis in the analytical electron microscope is used to measure the elemental composition at grain boundaries in the vicinity of carbides in sensitized specimens. Failure analysis of corrosion on stainless steel fasteners. Duplex stainless steel welds and their susceptibility to. Evaluation of sensitization in stainless steel 304 and. Practical guidelines for the fabrication of high performance. Phase diagrams and microstructure stainless steels. Heat affected zone haz can lose corrosion properties in ferritic steels and reason for that need not be sensitization.
The nose of this curve specifies the critical temperature at which the minimum time t min is required for sensitization. The bolts exhibited corrosion predominantly on the head of the bolt around the set screw, underneath the head of the bolt, and in the threads. Sep 03, 2015 austenitic stainless steels containing more than about 0. Formation of cr23c6 during the sensitization of aisi 304 stainless. Chemical composition of high performance austenitic stainless steels and representative standard grades wt. These steel exhibit good ductility, formability and moderately better yield strength, but the high temperature strength is somewhat poor saturation in austenite, and diffusion rates are. Mount of the sensitization of material is characterized by the degree of sensitization dos. An overview of sensitization dynamics in ferritic stainless. Sensitization evaluation of the austenitic stainless steel aisi 304l, 316l, 321 and 347 article in journal of materials science 401. Continuous cooling sensitization and its evaluation in.
Abstractthe chromium concentration along grain boundaries of sensitized austenitic 308 stainless steel was measured as a function of sensitizing treatment. Effect of sensitization on microhardness and corrosion. Theory of sensitization in ferritic stainless steel welds. Effect of solution treatment conditions on the sensitization of austenitic stainless steel xiaofei yu1, shenhao chen1,2 and liang wang1 1department of chemistry, shandong university, jinan 250100 and 2state key laboratory for corrosion and protection, shenyang 110016, pr china received 5 february, revised 27 may 2009. Material safety data sheet stainless steel section 1. Intergranular corrosion induced by environmental stresses is termed stress corrosion cracking. Time temperature sensitization tts diagrams for types. The information provided with this sds is furnished in good faith and without warranty of any kind.
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